CoP for hydrogen evolution: implications from hydrogen adsorption
نویسندگان
چکیده
منابع مشابه
Hydrogen Adsorption on Activated Carbon
The adsorption of hydrogen on carbon nanotubes and activated carbons has generated considerable interest in relation to hydrogen storage for fuel cells applications[1-3]. However, the widespread use of hydrogen as a fuel is limited by the lack of a convenient and cost-effective method of hydrogen storage. Adsorption of supercritical hydrogen is limited by the low interaction energy between hydr...
متن کاملHydrogen Adsorption on (5,0) and (3,3) Na-decorated BNNTs
The storage capacity of hydrogen on Na-decorated born nitride nanotubes (BNNTs) is investigated by using density functional theory within Quantum Espresso and Gaussian 09. The results obtained predict that a single Na atom tends to occupy above the central region of the hexagonal rings in (5,0) and (3,3) BNNT structures with a binding energy of -2.67 and -4.28 eV/Na-atom respectively. When a si...
متن کاملHydrogen evolution activity of NiMo-MoO2 produced by mechanical milling
In this study, mechanical alloying was done by a high-energy planetary ball milling technique. A mixture of NiO and MoO3 and graphite powders were used as initial materials. After milling of powder mixture with 40 wt.% additional graphite, a temperature of 400, 550 and 1000 °C for 1 h was considered for the heat treatment of powder mixture. Also, powder mixtures containing 60, 80 and 100 wt.% a...
متن کاملOperando Spectroscopic Analysis of CoP Films Electrocatalyzing the Hydrogen-Evolution Reaction.
Transition metal phosphides exhibit high catalytic activity toward the electrochemical hydrogen-evolution reaction (HER) and resist chemical corrosion in acidic solutions. For example, an electrodeposited CoP catalyst exhibited an overpotential, η, of -η < 100 mV at a current density of -10 mA cm-2 in 0.500 M H2SO4(aq). To obtain a chemical description of the material as-prepared and also while...
متن کاملThree-dimensional interconnected network of nanoporous CoP nanowires as an efficient hydrogen evolution cathode.
For the first time we demonstrate the topotactic synthesis of a three-dimensional (3D) interconnected network of nanoporous CoP nanowires directly on a Ti substrate (np-CoP NWs/Ti) via low-temperature phosphidation of a Co2(OH)2(CO3)2/Ti precursor and its further use as a highly efficient hydrogen evolution cathode.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2016
ISSN: 1463-9076,1463-9084
DOI: 10.1039/c6cp04011j